Are you suggesting a 5 day split with 3 exercises each day: Chest, back, biceps, triceps, and legs? With the option to combine chest and triceps, and back and biceps if necessary. I myself think that legs are more important than biceps and deserve more attention, not less(biceps will be worked by most back exercises too). 6 sets seems a bit light for weekly leg volume.
Why do you want her to do a body part split over an upper/lower split, or a push/pull/legs split? What do you mean by pretty good shape? Does she have much history lifting weights, or is her "pretty good shape" from sports, cardio, aerobics class. For the most part a good routine for a man is a good routine for a woman. By tone, do you mean that she needs to loose fat, or gain muscle, or both? Either way a consistent workout and disiplined diet can provide both.
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