If you've got the patience/diligence for carefully planning what and when you eat, you could try a plan like this one.
Kelly Bagget Thread on losing fat while gaining muscle
It proposes a carefully planned schedule to burn fat and build muscle.
There are similar plans/suggestions from others, as well. Most involve eating relatively high protein/high fat/low carb at most times, and eating higher carbs, lower fat around workout times.
Here's Berardi's version (it's the last Q&A in the article).
Appetite For Construction, Dec 5 2003
Other than something like this, you're bound to gain some fat along with muscle, like the others have said.
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Lost Dog's Blog & Workout Log
Superman never made any money
saving the world from Solomon Grundy
and sometimes I despair the world will never see
another man like him
-Crash Test Dummies. "Superman's Song"