I've found the late morning to be the ideal workout time. This only works for people who can decide upon their own hours and work later in the day.
In the late afternoon or evening I tend to be tired from other activities.
As for ROM etc.. do a general warm-up and if you're doing more difficult stuff, a specific warm-up too.. for squats & DLs that would be just lighter stuff.
For Oly exercises requiring flexibility, lots of preparatory 'stuff' with an empty bar or even broomstick. Especially when you like me have only half the ROM upon waking than when properly warmed up.
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